Products
CHLOROTHALONIL
Fungicide
FRAC Y; multi-site: chloronitrile
NOMENCLATURE
Common name chlorothalonil (BSI, E-ISO, (m) F-ISO, ANSI); TPN
(JMAF)
IUPAC name tetrachloroisophthalonitrile
Chemical Abstracts name 2,4,5,6-tetrachloro-1,3-benzenedicarbonitrile
CAS RN [1897-45-6] EEC no. 217-588-1 Development
codes DS-2787 (Diamond Shamrock)
PHYSICAL CHEMISTRY
Composition Tech. is c. 97%. Mol. wt. 265.9 M.f. C8Cl4N2 Form Colourless,
odourless crystals; (tech. has a slightly pungent odour). M.p. 252.1 °C B.p. 350 ºC/760
mmHg V.p. 0.076 mPa (25 ºC) KOW logP
= 2.92 (25 °C) Henry 2.50 × 10-2 Pa m3 mol-1
(25 °C) S.g./density 2.0 (20 °C) Solubility In
water 0.81 mg/l (25 ºC). In xylene 80, cyclohexanone, dimethylformamide
30, acetone, dimethyl sulfoxide 20, kerosene <10 (all in g/kg, 25 ºC). Stability Thermally
stable at ambient temperatures. Stable to u.v. light in aqueous media and in
crystalline state. Stable in acidic and moderately alkaline aqueous solutions;
slow hydrolysis at pH >9.
APPLICATIONS
Biochemistry Conjugation with, and depletion of, thiols (particularly
glutathione) from germinating fungal cells, leading to disruption of glycolysis
and energy production, fungistasis and fungicidal action. Mode
of action Non-systemic foliar fungicide with protective action. Uses Control
of many fungal diseases in a wide range of crops, including pome fruit, stone
fruit, citrus fruit, bush and cane fruit, cranberries, strawberries, pawpaws,
bananas, mangoes, coconut palms, oil palms, rubber, pepper, vines, hops, vegetables,
cucurbits, tobacco, coffee, tea, rice, soya beans, peanuts, potatoes, sugar beet,
cotton, maize, ornamentals, mushrooms, and turf. Application rates for food crops
are 1-2.5 kg/ha. Phytotoxicity Russetting is possible
with flowering ornamentals, apples, and grapes. Some varieties of flowering ornamentals
may be injured. Pittosporum foliage is sensitive. Phytotoxicity may
be increased with oils or oil-containing substances. Formulation
types SC; WG; WP; Fogging concentrate. Compatibility Not
compatible with oils.